Accessible #62

Water has a high heat of vaporization

The heat of vaporization of water is one of the highest of all liquids.

Scientific Explanation

To completely convert one liter of water at 100 degrees Celsius into steam requires about 2260 kilojoules — enough energy to heat the same liter of water from 0 to 540 degrees Celsius, if that were possible. This value is nearly three times higher than for ethanol (846 kJ/kg) and more than five times higher than for benzene (394 kJ/kg).

The cause lies in hydrogen bonds. During vaporization, every molecule must be pulled out of the liquid network, meaning all bonds to its neighbors must be broken simultaneously. Since each water molecule participates in up to four hydrogen bonds, each with a binding energy of about 20 kilojoules per mole, the total energy requirement is extraordinarily high.

For comparison, ethanol also forms hydrogen bonds, but only about two per molecule. Benzene has none at all — only weak dispersion forces hold its molecules together.

Heat of Vaporization Comparison Bar chart comparing the heat of vaporization of water (2260 kJ per kg), ethanol (846 kJ per kg), acetone (539 kJ per kg), and benzene (394 kJ per kg). Water requires far more energy to vaporize than comparable liquids. Heat of Vaporization (kJ/kg) 0 1200 2400 2260 Water 846 Ethanol 539 Acetone 394 Benzene Heat of Vaporization Comparison
Heat of vaporization of common liquids. Water requires by far the most energy to vaporize.

Step by Step

05001000150020002500020406080100120Energy (kJ/kg)Temperature (°C)2260 kJ/kgH₂O2260 kJ/kgEtOH840 kJ/kgAcetone520 kJ/kg

Adding Energy

We heat water starting at room temperature. The x-axis shows energy input in kilojoules per kilogram, the y-axis shows temperature in degrees Celsius.

Temperature Rises

Temperature climbs steadily from 20 to 100 degrees Celsius. Water needs 4.18 kJ/kg per degree -- already unusually high for a liquid.

The Plateau

At 100 degrees Celsius something remarkable happens: temperature stays constant even though energy keeps flowing in. All energy goes into the phase change -- liquid water becomes steam.

The Comparison

Water needs 2260 kJ/kg to vaporize -- nearly three times more than ethanol (840 kJ/kg) and over four times more than acetone (520 kJ/kg). The reason: each molecule must break up to four hydrogen bonds simultaneously.

Everyday Relevance

The high heat of vaporization is why sweating cools us: when sweat evaporates from the skin, it removes large amounts of heat from the body. Evaporating just a few milliliters is enough to noticeably lower the temperature. Wet clothing feels cold for the same reason — the evaporating water draws heat from the fabric and the skin.

In nature, the high heat of vaporization regulates climate: evaporation over the oceans transfers enormous amounts of energy into the atmosphere, which is released again during cloud formation and precipitation. This water cycle is one of the most important heat pumps on Earth.

Interactive Simulation

0500100015002000250030003500-20020406080100120140160180200Energy (kJ)Temperature (°C)-20°C | Ice
0 kJ